Design of a sustainable biofilter to remove pollutants from well water using chitosan, date pits, zeolite and orange peels
DOI:
https://doi.org/10.61856/kaqhrp30Keywords:
Bio-water filter, Groundwater treatment , Al-Hamdaniya wells, Physicochemical properties , Sustainable water purificationAbstract
This study aims to evaluate the efficiency of a low-cost bio-based water filter composed of natural materials (chitosan, zeolite, date seed powder, and orange peel powder) in improving the quality of groundwater from wells in the Nineveh Plain to meet the national drinking water standards. Physical and chemical analyses were conducted before and after filtration, including pH, electrical conductivity (EC), turbidity, major ions, heavy metals, and chemical oxygen demand (COD).The results showed a significant reduction in contaminant levels after treatment, with removal efficiencies ranging from 35% to 83% depending on the parameter. The highest removals were observed for heavy metals such as copper (83%), zinc (81%), and iron (83%), along with a COD reduction of up to 82%. Total dissolved solids and turbidity were also notably decreased, and most final values complied with the permissible limits.These findings demonstrate that the proposed bio-based water filter is an effective, sustainable, and affordable solution for areas with limited resources and high-water contamination levels. It is recommended to implement this design in rural communities and to further develop it by adding disinfection layers or optimizing contact time to enhance performance
References
Ahmad, M., Rajapaksha, A. U., Lim, J. E., Zhang, M., Bolan, N., Mohan, D., Vithanage, M., Lee, S. S., & Ok, Y. S. (2014). Biochar as a sorbent for contaminant management in soil and water: A review. Chemosphere, 99, 19–33. https://doi.org/10.1016/j.chemosphere.2013.10.071
Ajmal, M., Rao, R. A. K., Ahmad, R., & Ahmad, J. (2003). Adsorption studies on Citrus reticulata (fruit peel of orange): Removal and recovery of Ni(II) from electroplating wastewater. Journal of Hazardous Materials, 79(1–3), 117–131. https://doi.org/10.1016/S0304-3894(00)00302-4
Ali, I. (2010). New generation adsorbents for water treatment. Chemical Reviews, 110(10), 6856–6877. https://doi.org/10.1021/cr100008p
Alzahrani, S. M., & El-Ashgar, N. M. (2018). Removal of heavy metals from wastewater using chitosan beads. International Journal of Biological Macromolecules, 120, 1789–1794. https://doi.org/10.1016/j.ijbiomac.2018.09.151
Bilal, M., Asgher, M., & Iqbal, H. M. N. (2018). Advances in chitosan-based adsorbents for sustainable water treatment: A critical review. International Journal of Biological Macromolecules, 115, 647–665. https://doi.org/10.1016/j.ijbiomac.2018.04.035
Boussahel, A., & Addoun, F. (2020). Adsorption of heavy metals from aqueous solutions using natural zeolites: A review. Environmental Science and Pollution Research, 27(25), 31177–31198. https://doi.org/10.1007/s11356-020-09596-2
Crini, G. (2006). Non-conventional low-cost adsorbents for dye removal: A review. Bioresource Technology, 97(9), 1061–1085. https://doi.org/10.1016/j.biortech.2005.05.001
Dutta, P. K., Dutta, J., & Tripathi, V. S. (2004). Chitin and chitosan: Chemistry, properties and applications. Journal of Scientific & Industrial Research, 63(1), 20–31.
Fan, L., Li, J., Liu, Y., & Wang, Z. (2016). Removal of heavy metals from aqueous solutions by zeolite synthesized from coal fly ash: Adsorption equilibrium and kinetics. Chemical Engineering Journal, 298, 16–25. https://doi.org/10.1016/j.cej.2016.04.009
Foo, K. Y., & Hameed, B. H. (2010). Insights into the modeling of adsorption isotherm systems. Chemical Engineering Journal, 156(1), 2–10. https://doi.org/10.1016/j.cej.2009.09.013
Guibal, E. (2004). Activated carbons for the removal of metals from aqueous solutions. Environmental Science and Pollution Research, 11(2), 131–139. https://doi.org/10.1007/BF02987564
Ho, Y. S., & McKay, G. (1999). Pseudo-second order model for sorption processes. Process Biochemistry, 34(5), 451–465. https://doi.org/10.1016/S0032-9592(98)00112-5
Huang, C., & Yang, J. (2021). Biopolymer-based adsorbents for heavy metal removal: A review. Environmental Science and Pollution Research, 28(3), 2667–2684. https://doi.org/10.1007/s11356-020-10859-9
Karthikeyan, T., & Rajendran, S. (2017). Removal of heavy metals from aqueous solutions by adsorption on to orange peel. Applied Water Science, 7(3), 1535–1543. https://doi.org/10.1007/s13201-016-0453-8
Kumar, M. N. V. R. (2000). A review of chitin and chitosan applications. Reactive and Functional Polymers, 46(1), 1–27. https://doi.org/10.1016/S1381-5148(00)00038-9
Li, Q., Mahendra, S., Lyon, D. Y., Brunet, L., Liga, M. V., Li, D., & Alvarez, P. J. J. (2008). Antimicrobial nanomaterials for water disinfection and microbial control: Potential applications and implications. Water Research, 42(18), 4591–4602. https://doi.org/10.1016/j.watres.2008.09.031
Li, X., Zhang, W., & Han, M. (2019). Removal of heavy metals from aqueous solution using modified zeolite: Equilibrium, kinetics, and thermodynamics study. Environmental Science and Pollution Research, 26(22), 22552–22561. https://doi.org/10.1007/s11356-019-06075-7
Liu, H., Zhang, Y., & Liu, W. (2017). Adsorption of heavy metals on biochar derived from orange peel: Equilibrium and kinetic studies. Environmental Science and Pollution Research, 24(15), 13303–13313. https://doi.org/10.1007/s11356-017-9519-5
Mohan, D., & Pittman, C. U. (2006). Activated carbons and low-cost adsorbents for remediation of tri- and hexavalent chromium from water. Journal of Hazardous Materials, 137(2), 762–811. https://doi.org/10.1016/j.jhazmat.2006.04.064
Natarajan, E., & Sulochana, N. (2016). Removal of heavy metals from aqueous solution using low cost adsorbents – A review. International Journal of Engineering Research & Technology, 5(3), 322–328.
Nguyen, T. H., Nguyen, T. T., & Nguyen, V. M. (2020). Adsorption of Pb(II) and Cd(II) from aqueous solution by chitosan/zeolite composite: Isotherm and kinetics studies. Environmental Technology & Innovation, 19, 100898. https://doi.org/10.1016/j.eti.2020.100898
Okoye, P. U., Okafor, U. V., & Agbafor, K. N. (2021). Adsorption of heavy metals using date seed powder: A sustainable approach. Sustainable Chemistry and Pharmacy, 19, 100361. https://doi.org/10.1016/j.scp.2021.100361
Pradhan, N. C., & Das, S. N. (2020). Adsorptive removal of heavy metals using orange peel biochar: A review. Environmental Technology & Innovation, 20, 101095. https://doi.org/10.1016/j.eti.2020.101095
Qiu, H., Lv, L., Pan, B., Zhang, Q., Zhang, W., & Zhang, S. (2010). Critical review in adsorption kinetic models. Journal of Zhejiang University SCIENCE A, 10(5), 716–724. https://doi.org/10.1631/jzus.A1000134
Shahid, M., & Ashraf, M. A. (2013). Chromium occurrence in the environment and methods of its removal—a review. Environmental Monitoring and Assessment, 185, 8147–8163. https://doi.org/10.1007/s10661-013-3478-8
Tang, J., Zeng, G., Gong, J., Liang, J., Chen, Y., Liu, H., & Zhang, C. (2015). Effective removal of heavy metals from aqueous systems with nano-adsorbents: A review. Environmental Science and Pollution Research, 22(22), 17853–17871. https://doi.org/10.1007/s11356-015-5606-6
Wang, S., & Peng, Y. (2010). Natural zeolites as effective adsorbents in water and wastewater treatment. Chemical Engineering Journal, 156(1), 11–24. https://doi.org/10.1016/j.cej.2009.10.029
Wang, Y., Li, J., Zhang, Z., & Yu, X. (2017). Removal of heavy metals from water by bioadsorption using chitosan composites. Journal of Water Process Engineering, 18, 146–153. https://doi.org/10.1016/j.jwpe.2017.04.010
Younes, I., & Rinaudo, M. (2015). Chitin and chitosan preparation from marine sources. Structure, properties and applications. Marine Drugs, 13(3), 1133–1174. https://doi.org/10.3390/md13031133
Zhang, L., & Zhao, Y. (2019). Utilization of fruit peels for adsorption of heavy metals: A review. Critical Reviews in Environmental Science and Technology, 49(7), 639–658. https://doi.org/10.1080/10643389.2018.1538677
Zhang, W., Chen, X., Li, Y., & Zhao, H. (2023). Recent advances in sustainable biofilters for heavy metal removal. Journal of Environmental Management, 330, 117139. https://doi.org/10.1016/j.jenvman.2022.117139
Al-Juboori, R. A., & Yusaf, T. (2022). Sustainable low-cost bioadsorbents for water treatment: A review. Environmental Technology & Innovation, 27, 102523. https://doi.org/10.1016/j.eti.2022.102523
World Health Organization. (2022). Guidelines for drinking-water quality (4th ed.). Geneva: World Health Organization.
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